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Porous Stone ProtectorWater-based product specific for the water-repellent and oil-repellent treatment of stones:terracotta,tuff,cementitious supports and stone in general.Once completely dried it is invisible and the natural appearance of materials remains unaltered.Permeable to steam and gives the support a remarkable drop effect.
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Type of UseWater-based product specific for water repellent and oil repellent treatment of stones, matte
marble, terracotta, tuff, cementitious supports and stone in general. Penetrates deep down through the capillary
pores: up to a few millimetres within the materials. Once completely dried, the product is invisible
and the natural appearance of materials remains absolutely unaltered. Permeable to steam and
the breathability of the treated surfaces remains practically unchanged. Chemically stable and does not
alter as a result of exposure to U.V rays. Dries quickly and gives the support a remarkable
drop effect.Method of useThe surfaces to be treated must be clean and intact: remove friable parts and soluble salts and any moulds and/or algae with the aid of suitable products. The product is
ready for use and must be applied on completely dry surfaces, preferably cold or in any case not exposed to strong sunlight. Low pressure airless spray guns, brushes or rollers
can be used for application. Maximum hydro-oil repellency is obtained with impregnation of the support until
saturation, but significant results are obtained already with wet-on-wet application of just two coats of product. The optimal amount to be applied based
on the desired result should always be decided by performing a preliminary test on a small area. Complete water repellency
is achieved within 24 hours of application. Note: Shake product before use. Protect vegetation and all surfaces that should not be treated.
CAUTION! ON SOME SURFACES, DUE TO THEIR COMPOSITION OR PREVIOUS NON-CLASSIFIABLE TREATMENTS, THE STONE
PROTECTOR MAY NOT ACHIEVE THE DESIRED PERFORMANCE. ALWAYS PERFORM A PREVENTIVE TEST ON A
SAMPLE SURFACE (1-2 m2), WAITING 24-48 HOURS. PRODUCT IS NOT SUITABLE FOR SMOOTH OR LOW ABSORBENT SURFACES.Consumption and yieldYield: depends on the conditions of the support.
Dilution: SHOULD NOT BE DILUTED.
Application: brush or low-pressure spray.Chemical-Physical PropertiesSpecific Weight kg/l : approx. 1.00
Dry residue % :
Ford Viscosity Cup n.4 :
Dust dry free :
Overcoating: 6-8 hours
Film properties: water-based product specific for the water-repellent and oil-repellent treatment of stones:terracotta,tuff,cementitious supports and stone in general.Once completely dried it is invisible and the natural appearance of materials remains unaltered.Permeable to steam and gives the support a remarkable drop effect.Safety data sheet of 7/9/2015, revision 1 SECTION 1: identification of the substance/mixture and of the company/firm1.1. Product IdentifierIdentification of the mixture:Trade name: STONE PROTECTORTrade code: E194 1.2. Relevant identified uses of the substance or mixture and uses not recommendedRecommended use:Water-based paint product.1.3. Information on the supplier of the safety data sheetSupplier:INDUSTRIA TOSCANA VERNICI S.p.A - Via Stradone di Rovezzano, 21 - 50136 FirenzeTel. 055.690158 r.a.Fax 055.690246email: firstname.lastname@example.org: 7:30am-12:00pm/1:30pm-5:30pm Person responsible for the Safety Data Sheet:email@example.com Tel. 055.690158 r.a. Fax 055.6902461.4. Emergency telephone numberTel. 055.690158 r.a.Fax 055.690246email: firstname.lastname@example.org: 7:30am-12:00pm/1:30pm-5:30pm SECTION 2: hazards identification2.1. Classification of the substance or mixtureEC Regulation Criteria 1272/2008 (CLP):The product is not considered to be hazardous according to EC Regulation 1272/2008 (CLP).Physical-chemical effects harmful to human health and the environment:No other hazard2.2. Label elementsThe product is not considered to be hazardous in accordance with EC Regulation 1272/2008 (CLP).Symbols:NoneHazardIndications:NoneCautionsForPrudence:NoneSpecialDevices:NoneContains:Mixture of: 5-chlorine-2-methyl-2H-isothiazole-3-one [EC no. 247-500-7]; 2-methyl-2H-isothiazole-3-one [EC no. 220-239-6] (3:1): Can cause an allergic reaction.Special provisions based on REACH Annex XVII and subsequent adaptations:None2.3. Other hazardsvPvB substances: None - PBT substances: NoneOther hazards:No other hazards SECTION 3: composition/information on ingredients3.1. SubstancesN.A.3.2. MixtureHazardous components in accordance with Regulation CLP and relative classification:Qty NameID numb.Classification5 ppmMixture of: 5-chlorine-2-methyl-2H-isothiazole-3-one [EC no. 247-500-7]; 2-methyl-2H-isothiazole-3-one [EC no. 220-239-6] (3:1)Index Number:613-167-00-5CAS:55965-84-93.2/1B Skin Corr. 1B H314
3.4.2/1-1A-1B Skin Sens. 1,1A,1B H317
4.1/A1 Aquatic Acute 1 H400
4.1/C1 Aquatic Chronic 1 H410
3.1/3/Oral Acute Tox. 3 H301
3.1/3/Dermal Acute Tox. 3 H311
3.1/3/Inhal Acute Tox. 3 H331 SECTION 4: first aid measures4.1. Description of first aid measuresIn case of contact with skin:Wash with plenty of soap and water.In case of contact with eyes:In case of contact with eyes, wash immediately and thoroughly with water and consult a doctor.In case of ingestion: Do not induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION.In case of inhalation:Bring the victim in the open air and keep him warm and at rest.4.2. Main symptoms and effects, both acute and delayedNone4.3. Indication of any need to immediately consult a doctor and special treatmentsTreatment:None SECTION 5: fire-fighting measures5.1. Extinguishing measuresSuitable extinguishing means:Carbon dioxide (CO2).Extinguishing means which must not be used for safety reasons:DO NOT USE WATER EXTINGUISHERS.5.2. Special hazards arising from the substance or mixtureDo not inhale the gases produced by the explosion and combustion.Combustion produces heavy smoke.5.3. Advice for fire-fightersUse appropriate respiratory equipment.Separately collect the contaminated water used to extinguish the fire. Do not discharge it into the sewage system.If feasible from a safety point of view, move undamaged containers from the immediate danger area. SECTION 6: measures in case of accidental release6.1. Personal precautions, protective equipment and procedures in case of emergencyWear personal protective equipment.Remove all sources of ignition.Move people to a safe place.Consult the protective measures contained in points 7 and 8.6.2. Environmental precautionsPrevent penetration into the soil/subsoil. Prevent run-off into surface water or into the sewage system.Retain contaminated washing water and eliminate it.Inform the responsible authorities in the case of a gas leak or penetration into waterways, soil or sewer system.Suitable material for collection: absorbent, organic material, sand6.3. Methods and materials for containment and cleaning upWash with plenty of water.6.4. Reference to other sectionsSee also paragraph 8 and 13 SECTION 7: handling and storage7.1. Precautions for safe handlingAvoid contact with skin and eyes, inhalation of vapours and mists.Do not eat or drink during work.See also paragraph 8 for recommended protective equipment.7.2. Conditions for safe storage, including any incompatibilitiesKeep away from food, drink and feed.Incompatible materials:None in particular.Indication for premises:Properly ventilated rooms.7.3. Special end usesNo special uses SECTION 8: exposure control/individual protection8.1. Control parametersNo occupational exposure limits are availableExposure limit values DNELN.A.Exposure limit values PNECN.A.8.2. Exposure checksEye protection:Not required for normal use. Operate according to good work practices.Skin protection:The adoption of any special precautions for normal use is not required.Hand protection:Not required for normal use.Respiratory protection:Not necessary for normal use.Thermal risks:NoneEnvironmental exposure checks:NoneSuitable technical checks:None SECTION 9: physical and chemical properties9.1. Information on basic physical and chemical properties Properties ValueMethod:Notes:Appearance and colour:Clear liquid almost odourless----Odour:N.A.----Odour thresholdN.A.----pH:7----Melting/freezing point:n.d.----Initial boiling point and boiling interval:n.d.----Flash point:n.d.----Evaporation rate:N.A.----Solid/gas flammability:N.A.----Upper/lower flammability or explosion limit:N.A.----Steam pressure:N.A.----Steam density:N.A.----Relative density:1,000 kg/litre----Water solubility:Miscible ----Solubility in oil:N.A.---Partition coefficient (n-octanol/water):N.A.----Auto-ignition temperature:n.d.----Decomposition temperature:N.A.----Viscosity :N.A.----Explosive properties:N.A.----Oxidising properties:N.A.----9.2. Other information Properties ValueMethod:Notes:Miscibility :N.A.----Fat solubility :N.A.----Conductivity:N.A.----Characteristic properties of the groups of substances N.A.----SECTION 10: stability and reactivity 10.1. Reactivity Stable in normal conditions10.2. Chemical stabilityStable in normal conditions10.3. Possibility of dangerous reactionsNone10.4. Conditions to avoidStable in normal conditions.10.5. Incompatible materialsNone in particular.10.6. Hazardous decomposition products SECTION 11: toxicological information11.1. Information on toxicological effectsToxicological information regarding the mixture:N.A.Toxicological information concerning the main substances present in the mixture:N.A.Unless otherwise specified, data required by Regulation (EU)2015/830 indicated below are to be understood as N.A.:a) acute toxicity;b) skin corrosion/irritation;c) serious eye damage/irritation d) respiratory or skin sensitiser;e) germ cell mutagenicity;f) carcinogenicity;g) reproductive toxicity;h) specific toxicity for target organs (STOT) — single exposure;i) specific toxicity for target organs (STOT) — repeated exposure;j) aspiration hazard. SECTION 12: ecological information12.1. Toxicity Use according to good working practices, avoiding to disperse the product in the environment. Mixture of: 5-chlorine-2-methyl-2H-isothiazole-3-one [EC no. 247-500-7]; 2-methyl-2H-isothiazole-3-one [EC no. 220-239-6] (3:1) - CAS: 55965-84-9a) Acute aquatic toxicity:Endpoint: LC50 - Species: Fish 0.188 mg/L - Duration h: 96Endpoint: EC50 - Species: Daphnia 0.126 mg/L - Duration h: 48Endpoint: EC50 - Species: Algae 0.027 mg/L - Duration h: 7212.2. Persistence and degradability NoneN.A.12.3. Bioaccumulative potentialN.A.12.4. Mobility in soilN.A.12.5. Results of PBT and vPvB assessmentvPvB Substances: None - PBT substances: None12.6. Other adverse effectsNone SECTION 13: considerations on disposal13.1. Waste treatment methodsRecovery if possible. Operate according to local and national regulations. SECTION 14: information on transport14.1. UN NumberNot classified as a dangerous good under transport regulations.14.2. UN shipping name.A.14.3. Danger classes related to transportN.A.14.4. Packing groupN.A.14.5. Hazards for the environmentN.A.14.6. Special precautions for usersN.A.14.7. Transport in bulk according to Annex II of MARPOL and IBCN code.A. SECTION 15: regulatory information15.1. Legislative and regulatory provisions on health, safety and environment specific to the substance or mixtureLeg.Decr. 9/4/2008 n. 81D.M. Workplace 26/02/2004 (Occupational exposure limits)Regulation (EC) no. 1907/2006 (REACH)Regulation (EC) no. 1272/2008 (CLP)Regulation (EC) no. 790/2009 (ATP 1 CLP) and (EU) no. 758/2013Regulation (EU) 2015/830Regulation (EU) no. 286/2011 (ATP 2 CLP)Regulation (EU) no. 618/2012 (ATP 3 CLP)Regulation (EU) no. 487/2013 (ATP 4 CLP)Regulation (EU) no. 944/2013 (ATP 5 CLP)Regulation (EU) no. 605/2014 (ATP 6 CLP)Restrictions related to the product or to the substances contained according to Annex XVII of Regulation (EC) 1907/2006 (REACH) and subsequent amendments:Restrictions related to the product:Restriction 40Restrictions on the substances contained:No restriction.Where applicable, refer to the following regulations:Ministerial circulars 46 and 61 (Aromatic amines)Leg.Decr. 21 September 2005 no. 238 (Seveso Ter Directive)Regulation 648/2004/C (Detergents).L.D. 3/4/2006 no. 152 Rules on the environment Provisions relating to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): N.A.15.2. Evaluation of chemical safetyNo SECTION 16: other informationText from the sentences used in paragraph 3:H314 Causes serious skin burns and serious eye injuries.H317 May cause an allergic skin reaction.H400 Very toxic to aquatic organisms.H410 Very toxic to aquatic organisms with long lasting effects.H301 Toxic if swallowed.H311 Toxic in contact with skin.H331 Toxic if inhaled.This sheet has been reviewed in all its sections in accordance with Regulation 453/2010/EU.This document has been written by a competent SDS technician who has received appropriate training.Main bibliographic sources:NIOSH - Registry of toxic effects of chemical substances (1983)I.N.R.S. - Toxicological sheetCCNL - Annex 1 ''TLV for 1989-90''Higher Institute of Health - National Inventory of Chemical SubstancesThe information contained therein is based on our knowledge at the date stated above. It refers only to the product indicated and does not constitute a guarantee of particular quality.The user is required to ensure the suitability and completeness of such information in relation to the specific use that it must make.This sheet supersedes any previous editions. ADR:European Agreement concerning the international carriage of dangerous goods by road.CAS:Chemical Abstracts Service (division of the American Chemical Society).CLP:Classification, Labelling, Packaging.DNEL:Derived level without effect.EINECS:European inventory of existing European chemicals on the market.GefStoffVO:Ordinance on hazardous substances in Germany.GHS:Global harmonised classification and labelling system for chemical products.IATA:Association for international air transport.IATA-DGR:Dangerous Goods Regulation of the International Air Transport Association''(IATA).ICAO:International organisation for civil aviation.ICAO-TI:Technical instructions of the '' International Civil Aviation Organization'' (ICAO).IMDG:International Maritime Code for Dangerous Goods.INCI:International nomenclature of cosmetic ingredients.KSt:Explosion coefficient.LC50:Lethal concentration for 50 percent of the test population.LD50:Lethal dose for 50 percent of the test population.LTE:Long term exposure.PNEC:Concentration expected without effect.RID:Regulation concerning the international transport of dangerous goods by rail.STE:Short term exposure.STEL:Short-term exposure limit.STOT:Organ-specific toxicity.TLV:Threshold limit value.TWATLV:Threshold limit value for average weighed over 8 hours. (ACGIH Standard).WGK:Hazard class for water (Germany).